Ontology highlight
ABSTRACT:
SUBMITTER: Gianetti TL
PROVIDER: S-EPMC5811154 | biostudies-literature | 2015 Feb
REPOSITORIES: biostudies-literature
Gianetti Thomas L TL Nocton Grégory G Minasian Stefan G SG Kaltsoyannis Nikolas N Kilcoyne A L David ALD Kozimor Stosh A SA Shuh David K DK Tyliszczak Tolek T Bergman Robert G RG Arnold John J
Chemical science 20141111 2
Reaction of the neutral diniobium benzene complex {[Nb(BDI)N <sup><i>t</i></sup> Bu]<sub>2</sub>(μ-C<sub>6</sub>H<sub>6</sub>)} (BDI = <i>N</i>,<i>N</i>'-diisopropylbenzene-β-diketiminate) with Ag[B(C<sub>6</sub>F<sub>5</sub>)<sub>4</sub>] results in a single electron oxidation to produce a cationic diniobium arene complex, {[Nb(BDI)N <sup><i>t</i></sup> Bu]<sub>2</sub>(μ-C<sub>6</sub>H<sub>6</sub>)}{B(C<sub>6</sub>F<sub>5</sub>)<sub>4</sub>}. Investigation of the solid state and solution phase ...[more]