Unknown

Dataset Information

0

A Multifunctional Nanocage-based MOF with Tri- and Tetranuclear Zinc Cluster Secondary Building Units.

ABSTRACT: A new Zn-cluster based MOF, [Zn21(BTC)11(?3-OH)3(?4-O)3(H2O)18]·21EtOH (1) (H3BTC?=?1,3,5-benzenetricarboxylic acid), with two different types of cluster nodes has been successfully synthesized from Zn2+ and H3BTC under the solvothermal conditions. Single crystal X-ray diffraction studies reveal that 1 is a 3D trinodal (3,5,6)-c framework which features a large octahedral cage organized by nine Zn3O and nine Zn4O clusters SBUs and twenty-four triangular BTC3- linkers. The Eu3+/Tb3+-incorporated derivative of 1 with 0.251% Eu3+ and 0.269% Tb3+ exhibits tunable luminescence from yellow to white and then to blue-green by changing the excitation wavelength from 308 to 315?nm. Metal ion exchange with Cu2+ affords isomorphous Cu-based MOF with enhanced N2 and CO2 adsorption capacity. In addition, 1 can act as a selective luminescent sensor for Cu2+ and Al3+ ions.

SUBMITTER: Zhou Z 

PROVIDER: S-EPMC5814399 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

A Multifunctional Nanocage-based MOF with Tri- and Tetranuclear Zinc Cluster Secondary Building Units.

Zhou Zhongyuan Z   Xing Xiushuang X   Tian Chongbin C   Wei Wei W   Li Dejing D   Hu Falu F   Du Shaowu S  

Scientific reports 20180215 1

A new Zn-cluster based MOF, [Zn<sub>21</sub>(BTC)<sub>11</sub>(μ<sub>3</sub>-OH)<sub>3</sub>(μ<sub>4</sub>-O)<sub>3</sub>(H<sub>2</sub>O)<sub>18</sub>]·21EtOH (1) (H<sub>3</sub>BTC = 1,3,5-benzenetricarboxylic acid), with two different types of cluster nodes has been successfully synthesized from Zn<sup>2+</sup> and H<sub>3</sub>BTC under the solvothermal conditions. Single crystal X-ray diffraction studies reveal that 1 is a 3D trinodal (3,5,6)-c framework which features a large octahedral cage  ...[more]

Similar Datasets

Unknown A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building Units.
| S-EPMC5408180 | biostudies-literature
Unknown The Anisotropic Responses of a Flexible Metal-Organic Framework Constructed from Asymmetric Flexible Linkers and Heptanuclear Zinc Carboxylate Secondary Building Units.
| S-EPMC6778970 | biostudies-literature
Unknown 2D Porphyrinic Metal-Organic Frameworks Featuring Rod-Shaped Secondary Building Units.
| S-EPMC8156857 | biostudies-literature
Unknown Metal-organic frameworks constructed from monomeric, dimeric and trimeric phenanthroline citrate zinc building units.
| S-EPMC3600651 | biostudies-literature
Unknown Scalable units for building cardiac tissue.
| S-EPMC4245075 | biostudies-literature
Unknown Cobalt-bridged secondary building units in a titanium metal-organic framework catalyze cascade reduction of N-heteroarenes.
| S-EPMC6385530 | biostudies-other
Unknown Protein interface redesign facilitates the transformation of nanocage building blocks to 1D and 2D nanomaterials.
| S-EPMC8357837 | biostudies-literature
Genomics Transcriptional units form the elementary constraining building blocks of the bacterial chromosome
2023-12-01 | GSE213028 | GEO
Unknown Photocatalytic and Ferric Ion Sensing Properties of a New Three-Dimensional Metal-Organic Framework Based on Cuboctahedral Secondary Building Units.
| S-EPMC6649122 | biostudies-literature
Unknown Tri- and Tetranuclear Metal-String Complexes with Metallophilic d<sup>10</sup> -d<sup>10</sup> Interactions.
| S-EPMC6972983 | biostudies-literature