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Functionalization of N-arylglycine esters: electrocatalytic access to C-C bonds mediated by n-Bu4NI.

ABSTRACT: An efficient electrocatalytic functionalization of N-arylglycine esters is reported. The protocol proceeds in an undivided cell under constant current conditions employing the simple, cheap and readily available n-Bu4NI as the mediator. In addition, it is demonstrated that the mediated process is superior to the direct electrochemical functionalization.

SUBMITTER: Luo MH

PROVIDER: S-EPMC5827798 | biostudies-literature | 2018

REPOSITORIES: biostudies-literature

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Functionalization of N-arylglycine esters: electrocatalytic access to C-C bonds mediated by n-Bu4NI.

Luo Mi-Hai MH Jiang Yang-Ye YY Xu Kun K Liu Yong-Guo YG Sun Bao-Guo BG Zeng Cheng-Chu CC

Beilstein journal of organic chemistry 20180222

An efficient electrocatalytic functionalization of N-arylglycine esters is reported. The protocol proceeds in an undivided cell under constant current conditions employing the simple, cheap and readily available n-Bu4NI as the mediator. In addition, it is demonstrated that the mediated process is superior to the direct electrochemical functionalization. ...[more]

PMID: 29520311

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