Ontology highlight
ABSTRACT:
SUBMITTER: Chapovetsky A
PROVIDER: S-EPMC5879468 | biostudies-literature | 2018 Mar
REPOSITORIES: biostudies-literature
ACS central science 20180223 3
The bioinspired incorporation of pendant proton donors into transition metal catalysts is a promising strategy for converting environmentally deleterious CO<sub>2</sub> to higher energy products. However, the mechanism of proton transfer in these systems is poorly understood. Herein, we present a series of cobalt complexes with varying pendant secondary and tertiary amines in the ligand framework with the aim of disentangling the roles of the first and second coordination spheres in CO<sub>2</su ...[more]