Unknown

Dataset Information

0

Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes.


ABSTRACT: Helical organic micro- and nanostructures are formed by a charge-transfer complex, cinchonidine-TCNQ. These unusual forms result from the chirality, the steric structure and specific interactions of cinchonidine molecules. These materials are semiconductors (10-4?S?cm-1), with the typical absorption spectra in IR and UV-vis, but also have a characteristic of CD spectrum. Surprisingly, conductive micro and nano helices are not formed in pseudo-enantiomeric cinchonine, i.e. the complex of cinchonine and TCNQ.

SUBMITTER: Langer JJ 

PROVIDER: S-EPMC5882684 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature

altmetric image

Publications

Pseudo-enantiomeric chiral components and formation of the helical micro- and nanostructures in charge-transfer complexes.

Langer Jerzy J JJ   Hreczycho Grzegorz G  

Royal Society open science 20180314 3


Helical organic micro- and nanostructures are formed by a charge-transfer complex, cinchonidine-TCNQ. These unusual forms result from the chirality, the steric structure and specific interactions of cinchonidine molecules. These materials are semiconductors (10<sup>-4</sup> S cm<sup>-1</sup>), with the typical absorption spectra in IR and UV-vis, but also have a characteristic of CD spectrum. Surprisingly, conductive micro and nano helices are not formed in pseudo-enantiomeric cinchonine, i.e. t  ...[more]

Similar Datasets

| S-EPMC1914416 | biostudies-literature
| S-EPMC8395658 | biostudies-literature
| S-EPMC4660918 | biostudies-literature
| S-EPMC2680476 | biostudies-literature
| S-EPMC7708636 | biostudies-literature
| S-EPMC4394993 | biostudies-literature
| S-EPMC1162035 | biostudies-other
| S-EPMC5899485 | biostudies-other
| S-EPMC4442668 | biostudies-other
| S-EPMC9281308 | biostudies-literature