Ontology highlight
ABSTRACT:
SUBMITTER: Krekic K
PROVIDER: S-EPMC5888180 | biostudies-literature | 2018 Feb
REPOSITORIES: biostudies-literature
Zeitschrift fur anorganische und allgemeine Chemie 20180117 3
An improved synthesis using microwave heating affords (C<sub>6</sub>H<sub>4</sub>PO(OCH<sub>3</sub>)<sub>2</sub>)<sub>2</sub> in excellent isolated yield (95 %). The ligand properties of this bisphosphonateester were explored towards hard metal centers <i>M</i><sup>2+</sup> (<i>M</i> = Ca, UO<sub>2</sub>) and <i>M</i><sup>3+</sup> (<i>M</i> = La, Ce, Sm, Eu) resulting in coordination polymers, for which the reduction of ionic size of the central metal atom resulted in lower-dimensional structura ...[more]