Extraordinary pseudocapacitive energy storage triggered by phase transformation in hierarchical vanadium oxides.

ABSTRACT: Pseudocapacitance holds great promise for improving energy densities of electrochemical supercapacitors, but state-of-the-art pseudocapacitive materials show capacitances far below their theoretical values and deliver much lower levels of electrical power than carbon-based materials due to poor cation accessibility and/or long-range electron transferability. Here we show that in situ corundum-to-rutile phase transformation in electron-correlated vanadium sesquioxide can yield nonstoichiometric rutile vanadium dioxide layers that are composed of highly sodium ion accessible oxygen-deficiency quasi-hexagonal tunnels sandwiched between conductive rutile slabs. This unique structure serves to boost redox and intercalation kinetics for extraordinary pseudocapacitive energy storage in hierarchical isomeric vanadium oxides, leading to a high specific capacitance of ~1856?F?g-1 (almost sixfold that of the pristine vanadium sesquioxide and dioxide) and a bipolar charge/discharge capability at ultrafast rates in aqueous electrolyte. Symmetric wide voltage window pseudocapacitors of vanadium oxides deliver a power density of ~280?W?cm-3 together with an exceptionally high volumetric energy density of ~110?mWh?cm-3 as well as long-term cycling stability.

SUBMITTER: Liu BT 

PROVIDER: S-EPMC5893573 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature