Browse
Submit Data
Databases
API
Help

Dataset Information

27 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Highly stable graphene-oxide-based membranes with superior permeability.

ABSTRACT: Increasing fresh water demand for drinking and agriculture is one of the grand challenges of our age. Graphene oxide (GO) membranes have shown a great potential for desalination and water purification. However, it is challenging to further improve the water permeability without sacrificing the separation efficiency, and the GO membranes are easily delaminated in aqueous solutions within few hours. Here, we report a class of reduced GO membranes with enlarged interlayer distance fabricated by using theanine amino acid and tannic acid as reducing agent and cross-linker. Such membranes show water permeance over 10,000?L?m-2 h-1 bar-1, which is 10-1000 times higher than those of previously reported GO-based membranes and commercial membranes, and good separation efficiency, e.g., rhodamine B and methylene blue rejection of ~100%. Moreover, they show no damage or delamination in water, acid, and basic solutions even after months.

SUBMITTER: Thebo KH

PROVIDER: S-EPMC5902455 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Highly stable graphene-oxide-based membranes with superior permeability.

Thebo Khalid Hussain KH Qian Xitang X Zhang Qing Q Chen Long L Cheng Hui-Ming HM Ren Wencai W

Nature communications 20180416 1

Increasing fresh water demand for drinking and agriculture is one of the grand challenges of our age. Graphene oxide (GO) membranes have shown a great potential for desalination and water purification. However, it is challenging to further improve the water permeability without sacrificing the separation efficiency, and the GO membranes are easily delaminated in aqueous solutions within few hours. Here, we report a class of reduced GO membranes with enlarged interlayer distance fabricated by usi ...[more]

PMID: 29662053

Similar Datasets

Highly Selective Supported Graphene Oxide Membranes for Water-Ethanol Separation.

Project description:A polyethersulfone (PES)-supported graphene oxide (GO) membrane has been developed by a simple casting approach. This stable membrane is applied for ethanol/water separation at different temperatures. The 5.0 µm thick GO film coated on PES support membrane showed a long-term stability over a testing period of one month and excellent water/ethanol selectivity at elevated temperatures. The water/ethanol selectivity is dependent on ethanol weight percentage in water/ethanol feed mixtures and on operating temperature. The water/ethanol selectivity was enhanced with an increase of ethanol weight percentage in water/ethanol mixtures, from below 100 at RT to close to 874 at a 90 °C for 90% ethanol/10% water mixture. Molecular dynamics simulation of water-ethanol mixtures in graphene bilayers, that are considered to play a key role in transport, revealed that molecular transport is negligible for layer spacing below 1 nm. The differences in the diffusion of ethanol and water in the bilayer are not consistent with the large selectivity value experimentally observed. The entry of water and ethanol into the interlayer space may be the crucial step controlling the selectivity.

| S-EPMC6381104 | biostudies-literature

Recent Developments of Graphene Oxide-Based Membranes: A Review.

Project description:Membrane-based separation technology has attracted great interest in many separation fields due to its advantages of easy-operation, energy-efficiency, easy scale-up, and environmental friendliness. The development of novel membrane materials and membrane structures is an urgent demand to promote membrane-based separation technology. Graphene oxide (GO), as an emerging star nano-building material, has showed great potential in the membrane-based separation field. In this review paper, the latest research progress in GO-based membranes focused on adjusting membrane structure and enhancing their mechanical strength as well as structural stability in aqueous environment is highlighted and discussed in detail. First, we briefly reviewed the preparation and characterization of GO. Then, the preparation method, characterization, and type of GO-based membrane are summarized. Finally, the advancements of GO-based membrane in adjusting membrane structure and enhancing their mechanical strength, as well as structural stability in aqueous environment, are particularly discussed. This review hopefully provides a new avenue for the innovative developments of GO-based membrane in various membrane applications.

| S-EPMC5618137 | biostudies-literature

Ultrathin graphene oxide-based hollow fiber membranes with brush-like CO2-philic agent for highly efficient CO2 capture.

Project description:Among the current CO2 capture technologies, membrane gas separation has many inherent advantages over other conventional techniques. However, fabricating gas separation membranes with both high CO2 permeance and high CO2/N2 selectivity, especially under wet conditions, is a challenge. In this study, sub-20-nm thick, layered graphene oxide (GO)-based hollow fiber membranes with grafted, brush-like CO2-philic agent alternating between GO layers are prepared by a facile coating process for highly efficient CO2/N2 separation under wet conditions. Piperazine, as an effective CO2-philic agent, is introduced as a carrier-brush into the GO nanochannels with chemical bonding. The membrane exhibits excellent separation performance under simulated flue gas conditions with CO2 permeance of 1,020 GPU and CO2/N2 selectivity as high as 680, demonstrating its potential for CO2 capture from flue gas. We expect this GO-based membrane structure combined with the facile coating process to facilitate the development of ultrathin GO-based membranes for CO2 capture.

| S-EPMC5727382 | biostudies-literature

Oxidized Carbon-Based Spacers for Pressure-Resistant Graphene Oxide Membranes.

Project description:In this study, we report the influence of carbon-based spacer-oxidized derivatives of fullerenes (fullerenols) C60(OH)26-32 and graphene oxide nanoribbons on the performance and pressure stability of graphene-oxide-based composite membranes. The impact of the intercalant shape and composition on the permeance of the selective layers for water vapors has been studied under pressure gradients. It is shown that the insertion of ball-shaped fullerenols between graphene oxide nanoflakes allows a suppression in irreversible permeance loss to 2-4.5% and reversible permeance loss to <25% (at 0.1 MPa), while retaining large H2O/N2 selectivities of up to ~30,000. The demonstrated approach opens avenues for the highly effective stabilization of GO membranes at elevated pressures for industrial-scale dehumidification.

| S-EPMC9612342 | biostudies-literature

Highly stretchable and reliable graphene oxide-reinforced liquid gating membranes for tunable gas/liquid transport.

Project description:The ability of membrane technologies to dynamically tune the transport behavior for gases and liquids is critical for their applications. Although various methods have been developed to improve membrane success, tradeoffs still exist among their properties, such as permeability, selectivity, fouling resistance, and stability, which can greatly affect the performance of membranes. Existing elastomeric membrane designs can provide antifracture properties and flexibility; however, these designs still face certain challenges, such as low tensile strength and reliability. Additionally, researchers have not yet thoroughly developed membranes that can avoid fouling issues while realizing precise dynamic control over the transport substances. In this study, we show a versatile strategy for preparing graphene oxide-reinforced elastomeric liquid gating membranes that can finely modulate and dynamically tune the sorting of a wide range of gases and liquids under constant applied pressures. Moreover, the produced membranes exhibit antifouling properties and are adaptable to different length scales, pressures, and environments. The filling of graphene oxide in the thermoplastic polyurethane matrix enhances the composites through hydrogen bonds. Experiments and theoretical calculations are carried out to demonstrate the stability of our system. Our membrane exhibits good stretchability, recovery, and durability due to the elastic nature of the solid matrix and dynamic nature of the gating liquid. Dynamic control over the transport of gases and liquids is achieved through our optimized interfacial design and controllable pore deformation, which is induced by mechanical stimuli. Our strategy will create new opportunities for many applications, such as gas-involved chemical reactions, multiphase separation, microfluidics, multiphase microreactors, and particulate material synthesis.

| S-EPMC8433400 | biostudies-literature

Highly Permeable Sulfonated Graphene-Based Composite Membranes for Electrochemically Enhanced Nanofiltration.

Project description:A sulfophenyl-functionalized reduced graphene oxide (SrGO) membrane is prepared. The SrGO membranes have a high charge density in water and could provide many atomically smooth nanochannels, because of their strong ionized-SO3H groups and low oxygen content. Therefore, the SrGO membranes have an excellent performance in terms of high permeance and high rejection ability. The permeance of SrGO membranes could be up to 118.2 L m-2 h-1 bar-1, which is 7.6 times higher than that of GO membrane (15.5 L m-2 h-1 bar-1). Benefiting from their good electrical conductivity, the SrGO membranes could also function as an electrode and demonstrate a significantly increased rejection toward negatively charged molecules and positively charged heavy metal ions such as Cu2+, Cr3+ and Cd2+, if given an appropriate negative potential. The rejection ratios of these metal ions can be increased from <20% at 0 V to >99% at 2.0 V. This is attributed to the enhanced electrostatic repulsion between the SrGO membrane and the like-charged molecules, and the increased electrostatic adsorption and electrochemical reduction in these heavy metal ions on the membranes. This study is expected to contribute to efficient water treatment and the advance of graphene-based membranes.

| S-EPMC9370331 | biostudies-literature

Theoretical Analysis of Superior Photodegradation of Methylene Blue by Cerium Oxide/Reduced Graphene Oxide vs. Graphene.

Project description:Density functional theory and a semi-empirical quantum chemical approach were used to evaluate the photocatalytic efficiency of ceria (CeO2) combined with reduced graphene oxide (rGO) and graphene (GP) for degrading methylene blue (MB). Two main aspects were examined: the adsorption ability of rGO and GP for MB, and the separation of photogenerated electrons and holes in CeO2/rGO and CeO2/GP. Our results, based on calculations of the adsorption energy, population analysis, bond strength index, and reduced density gradient, show favorable energetics for MB adsorption on both rGO and GP surfaces. The process is driven by weak, non-covalent interactions, with rGO showing better MB adsorption. A detailed analysis involving parameters like fractional occupation density, the centroid distance between molecular orbitals, and the Lewis acid index of the catalysts highlights the effective charge separation in CeO2/rGO compared to CeO2/GP. These findings are crucial for understanding photocatalytic degradation mechanisms of organic dyes and developing efficient photocatalysts.

| S-EPMC11356922 | biostudies-literature

Graphene Oxide-Based Membranes Intercalated with an Aromatic Crosslinker for Low-Pressure Nanofiltration.

Project description:Graphene oxide (GO), a carbonaceous 2D nanomaterial, has received significant interest as a next-generation membrane building block. To fabricate high-performance membranes, an effective strategy involves stacking GO nanosheets in laminated structures, thereby creating unique nanochannel galleries. One outstanding merit of laminar GO membranes is that their permselectivity is readily tunable by tailoring the size of the nanochannels. Here, a high-performance GO-based nanofiltration membrane was developed by intercalating an aromatic crosslinker, α,α/-dichloro-p-xylene (DCX), between the layers in laminated GO nanosheets. Owing to the formation of strong covalent bonds between the crosslinker and the GO, the resulting GO laminate membrane exhibited outstanding structural stability. Furthermore, due to the precisely controlled and enlarged interlayer spacing distance of the developed DCX-intercalated GO membrane, it achieved an over two-fold enhancement in water permeability (11 ± 2 LMH bar-1) without sacrificing the rejection performance for divalent ions, contrary to the case with a pristine GO membrane.

| S-EPMC9612350 | biostudies-literature

Large-area graphene-based nanofiltration membranes by shear alignment of discotic nematic liquid crystals of graphene oxide.

Project description:Graphene-based membranes demonstrating ultrafast water transport, precise molecular sieving of gas and solvated molecules shows great promise as novel separation platforms; however, scale-up of these membranes to large-areas remains an unresolved problem. Here we demonstrate that the discotic nematic phase of graphene oxide (GO) can be shear aligned to form highly ordered, continuous, thin films of multi-layered GO on a support membrane by an industrially adaptable method to produce large-area membranes (13 × 14 cm(2)) in <5 s. Pressure driven transport data demonstrate high retention (>90%) for charged and uncharged organic probe molecules with a hydrated radius above 5 Å as well as modest (30-40%) retention of monovalent and divalent salts. The highly ordered graphene sheets in the plane of the membrane make organized channels and enhance the permeability (71 ± 5 l m(-2) hr(-1) bar(-1) for 150 ± 15 nm thick membranes).

| S-EPMC4786680 | biostudies-literature

Effect of Graphene Oxide Synthesis Method on Properties and Performance of Polysulfone-Graphene Oxide Mixed Matrix Membranes.

Project description:Graphene oxide (GO) has shown great promise as a nanofiller to enhance the performance of mixed matrix composite membranes (MMMs) for water treatment applications. However, GO can be prepared by various synthesis routes, leading to different concentrations of the attached oxygen functional groups. In this research, GO produced by the Hummers', Tour, and Staudenmaier methods were characterized and embedded at various fractions into the matrix of polysulfone (PSf) and used to prepare microfiltration membranes via the phase inversion process. The effects of the GO preparation method and loading on the membrane characteristics, as well as performance for oil removal from an oil-water emulsion, are analyzed. Our results reveal that GO prepared by the Staudenmaier method has a higher concentration of the more polar carbonyl group, increasing the membrane hydrophilicity and porosity compared to GO prepared by the Hummers' and Tour methods. On the other hand, the Hummers' and Tour methods produce GO with larger sheet size, and are more effective in enhancing the mechanical properties of the PSf membrane. Finally, all MMMs exhibited improved water flux (up to 2.7 times) and oil rejection, than those for the control PSf sample, with the optimum GO loading ranged between 0.1-0.2 wt%.

| S-EPMC6566723 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data