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The role of charge in 1,2,3-triazol(ium)-based halogen bonding activators.

ABSTRACT: The influence of charge on the performance of monocationic and dicationic triazol(ium)-based halogen bond donors was investigated. Next to the activity in a halide abstraction benchmark reaction, halogen bonding was also evaluated via X-ray structural analyses and isothermal titration calorimetry.

SUBMITTER: Dreger A 

PROVIDER: S-EPMC5933004 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature

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The role of charge in 1,2,3-triazol(ium)-based halogen bonding activators.

Dreger Alexander A   Engelage Elric E   Mallick Bert B   Beer Paul D PD   Huber Stefan M SM  

Chemical communications (Cambridge, England) 20180401 32

The influence of charge on the performance of monocationic and dicationic triazol(ium)-based halogen bond donors was investigated. Next to the activity in a halide abstraction benchmark reaction, halogen bonding was also evaluated via X-ray structural analyses and isothermal titration calorimetry. ...[more]

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