Ontology highlight
ABSTRACT:
SUBMITTER: Wang J
PROVIDER: S-EPMC5933225 | biostudies-literature | 2018 Apr
REPOSITORIES: biostudies-literature
Wang Jian J Kim Gakhyun G Sandoval-Salinas María Eugenia ME Phan Hoa H Gopalakrishna Tullimilli Y TY Lu Xuefeng X Casanova David D Kim Dongho D Wu Jishan J
Chemical science 20180228 13
We report the first class of stable, two-dimensional (2D) anti-ferromagnetically coupled dendritic polyradicaloids. A kinetically blocked fluorenyl radical was used to build up the first and second generation dendrons <b>FR-G1</b> and <b>FR-G2</b> containing three and seven fluorenyl units, respectively. The neighboring fluorenyl radicals in <b>FR-G1</b> and <b>FR-G2</b> show moderate anti-ferromagnetic exchange interaction, resulting in a doublet and quartet ground state, respectively, with a s ...[more]