Crystal structure and Hirshfeld surface analysis of di-aqua-bis-(N,N-di-ethyl-nicotinamide-κN¹)bis-(2,4,6-tri-methyl-benzoato-κO)manganese(II).

ABSTRACT: In the title centrosymmetric complex, [Mn(C₁₀H₁₁O₂)₂(C₁₀H₁₄N₂O)₂(H₂O)₂], the Mn^II cation is located on an inversion centre. The four O atoms form a slightly distorted square-planar arrangement around the Mn^II cation, and the distorted octa-hedral coordination is completed by two pyridine N atoms at distances of 2.3289 (15) Å. The dihedral angle between the planar carboxyl-ate group and the adjacent benzene ring is 87.73 (16)°, while the benzene and pyridine rings are oriented at a dihedral angle of 43.03 (8)°. In the crystal, the water mol-ecules are involved in both intra-molecular (to the non-coordinating carboxyl-ate O atom) and inter-molecular (to the amid

SUBMITTER: Hokelek T 

PROVIDER: S-EPMC5946959 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature