Dataset Information

Determination of association constants towards carbon nanotubes.

ABSTRACT: Single-walled carbon nanotubes (SWNTs) are one of the most promising nanomaterials and their supramolecular chemistry has attracted a lot of attention. However, despite well over a decade of research, there is no standard method for the quantification of their noncovalent chemistry in solution/suspension. Here, we describe a simple procedure for the determination of association constants (K_a) between soluble molecules and insoluble and heterogeneous carbon nanotube samples. To test the scope of the method, we report binding constants between five different hosts and two types of SWNTs in four solvents. We have determined numeric values of K_a in the range of 1-10⁴ M^-1. Solvent effects as well as structural changes in both the host and guest result in noticeable changes of K_a. The results obtained experimentally were validated through state-of-the-art DFT calculations. The generalization of quantitative and comparable association constants data should significantly help advance the supramolecular chemistry of carbon nanotubes.

SUBMITTER: de Juan A

PROVIDER: S-EPMC5947526 | biostudies-literature | 2015 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Determination of association constants towards carbon nanotubes.

de Juan Alberto A López-Moreno Alejandro A Calbo Joaquín J Ortí Enrique E Pérez Emilio M EM

Chemical science 20150907 12

Single-walled carbon nanotubes (SWNTs) are one of the most promising nanomaterials and their supramolecular chemistry has attracted a lot of attention. However, despite well over a decade of research, there is no standard method for the quantification of their noncovalent chemistry in solution/suspension. Here, we describe a simple procedure for the determination of association constants (<i>K</i><sub>a</sub>) between soluble molecules and insoluble and heterogeneous carbon nanotube samples. To ...[more]

PMID: 29861939

Similar Datasets

Project description:Optical absorption is the most fundamental optical property characterizing light-matter interactions in materials and can be most readily compared with theoretical predictions. However, determination of optical absorption cross-section of individual nanostructures is experimentally challenging due to the small extinction signal using conventional transmission measurements. Recently, dramatic increase of optical contrast from individual carbon nanotubes has been successfully achieved with a polarization-based homodyne microscope, where the scattered light wave from the nanostructure interferes with the optimized reference signal (the reflected/transmitted light). Here we demonstrate high-sensitivity absorption spectroscopy for individual single-walled carbon nanotubes by combining the polarization-based homodyne technique with broadband supercontinuum excitation in transmission configuration. To our knowledge, this is the first time that high-throughput and quantitative determination of nanotube absorption cross-section over broad spectral range at the single-tube level was performed for more than 50 individual chirality-defined single-walled nanotubes. Our data reveal chirality-dependent behaviors of exciton resonances in carbon nanotubes, where the exciton oscillator strength exhibits a universal scaling law with the nanotube diameter and the transition order. The exciton linewidth (characterizing the exciton lifetime) varies strongly in different nanotubes, and on average it increases linearly with the transition energy. In addition, we establish an empirical formula by extrapolating our data to predict the absorption cross-section spectrum for any given nanotube. The quantitative information of absorption cross-section in a broad spectral range and all nanotube species not only provides new insight into the unique photophysics in one-dimensional carbon nanotubes, but also enables absolute determination of optical quantum efficiencies in important photoluminescence and photovoltaic processes.

Dataset Information

Determination of association constants towards carbon nanotubes.

Publications

Determination of association constants towards carbon nanotubes.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets