Ontology highlight
ABSTRACT:
SUBMITTER: Grigoropoulos A
PROVIDER: S-EPMC5947555 | biostudies-literature | 2018 Apr
REPOSITORIES: biostudies-literature
Grigoropoulos Alexios A McKay Alasdair I AI Katsoulidis Alexandros P AP Davies Robert P RP Haynes Anthony A Brammer Lee L Xiao Jianliang J Weller Andrew S AS Rosseinsky Matthew J MJ
Angewandte Chemie (International ed. in English) 20180322 17
Crabtree's catalyst was encapsulated inside the pores of the sulfonated MIL-101(Cr) metal-organic framework (MOF) by cation exchange. This hybrid catalyst is active for the heterogeneous hydrogenation of non-functionalized alkenes either in solution or in the gas phase. Moreover, encapsulation inside a well-defined hydrophilic microenvironment enhances catalyst stability and selectivity to hydrogenation over isomerization for substrates bearing ligating functionalities. Accordingly, the encapsul ...[more]