Ontology highlight
ABSTRACT:
SUBMITTER: Hinz A
PROVIDER: S-EPMC5953028 | biostudies-literature | 2016 Jan
REPOSITORIES: biostudies-literature
Chemical science 20151027 1
The formal cyclopentane-1,3-diyl derivatives [E<sup>1</sup>(μ-NTer)<sub>2</sub>({E<sup>2</sup>C} = NDmp)] (Ter = 2,6-dimesityl-phenyl, Dmp = 2,6-dimethylphenyl) were prepared by 1,1-insertion of CNDmp into the N-E<sup>2</sup> bond of [E<sup>1</sup>(μ-NTer)<sub>2</sub>E<sup>2</sup>] (E<sup>1</sup> = N, P; E<sup>2</sup> = P, As). The insertion does not occur for E<sup>1</sup> = E<sup>2</sup> = As or E<sup>2</sup> = Sb. Dependent on the choice of formal radical centres E, either a biradicaloid or a ...[more]