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Crystal structure of 3-[(2-acetamido-phen-yl)imino]-butan-2-one.

ABSTRACT: In the title compound, 3-[(2-acetamido-phen-yl)imino]-butan-2-one, C12H14N2O2, the imine C=N bond is essentially coplanar with the ketone C=O bond in an s-trans conformation. The benzene ring is twisted away from the plane of the C=N bond by 53.03?(14)°. The acetamido unit is essentially coplanar with the benzene ring. In the crystal, mol-ecules are connected into chains along the c axis through C-H?O hydrogen bonds, with two adjacent chains being hinged by C-H?O hydrogen bonds.

SUBMITTER: Zhai F

PROVIDER: S-EPMC5956335 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of 3-[(2-acetamido-phen-yl)imino]-butan-2-one.

Zhai Feng F Solomon Joseph B JB Filatov Alexander S AS Jordan Richard F RF

Acta crystallographica. Section E, Crystallographic communications 20180119 Pt 2

In the title compound, 3-[(2-acetamido-phen-yl)imino]-butan-2-one, C12H14N2O2, the imine C=N bond is essentially coplanar with the ketone C=O bond in an s-trans conformation. The benzene ring is twisted away from the plane of the C=N bond by 53.03 (14)°. The acetamido unit is essentially coplanar with the benzene ring. In the crystal, mol-ecules are connected into chains along the c axis through C-H⋯O hydrogen bonds, with two adjacent cha ...[more]

PMID: 29850052

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