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Decoration of Pt on Cu/Co double-doped CeO2 nanospheres and their greatly enhanced catalytic activity.

ABSTRACT: In this paper, we report an efficient strategy for the synthesis of Cu/Co double-doped CeO2 nanospheres (Cu x Co1-x -CeO2-Pt, 0 ? x ? 1), which were fabricated via a simple water-glycol system. The following in situ surface decoration of Pt nanoparticles make these nanospheres highly active for the catalytic reduction of nitrophenol and CO oxidation. Detailed tests show that their catalytic performance strongly depends on the doping components and ion concentration of Cu and Co ions. The best samples of Cu0.50Co0.50-CeO2-Pt and Cu0.34Co0.66-CeO2-Pt demonstrate an excellent turnover frequency (TOF) of more than 450 h-1 after five cycles and retains about 99% conversion by using NH3BH3 as a reductant to reduce nitrophenol. Moreover, Cu0.50Co0.50-CeO2-Pt possesses a much lower light-off and T100 (the temperature for 100% CO oxidation) temperature compared with the other catalysts.

SUBMITTER: Wang F

PROVIDER: S-EPMC5965059 | biostudies-literature | 2016 Mar

REPOSITORIES: biostudies-literature

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Decoration of Pt on Cu/Co double-doped CeO2 nanospheres and their greatly enhanced catalytic activity.

Wang Fan F Li Wang W Feng Xilan X Liu Dapeng D Zhang Yu Y

Chemical science 20151125 3

In this paper, we report an efficient strategy for the synthesis of Cu/Co double-doped CeO2 nanospheres (Cu x Co1-x -CeO2-Pt, 0 ≤ x ≤ 1), which were fabricated via a simple water-glycol system. The following in situ surface decoration of Pt nanoparticles make these nanospheres highly active for the catalytic reduction of nitrophenol and CO oxidation. Detailed tests show that their catalytic performance strongly depend ...[more]

PMID: 29899909

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