Ontology highlight
ABSTRACT:
SUBMITTER: Cheng F
PROVIDER: S-EPMC5989696 | biostudies-literature | 2018 Jun
REPOSITORIES: biostudies-literature
Chemical science 20180430 22
Catalytic chemo- and enantioselective generation of tertiary benzylic copper complexes from Cu-B(pin) (pin = pinacolato) additions to 1,1-disubstituted alkenes followed by <i>in situ</i> reactions with ketones and carboxylic acid phenol esters to construct multifunctional alkylboron compounds that contain quaternary stereogenic centers is presented. The method is distinguished by the unprecedented reaction mode of tertiary benzylic Cu complexes, allowing reaction with a wide range of carbonyl el ...[more]