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Low-Cost Synthesis of Highly Luminescent Colloidal Lead Halide Perovskite Nanocrystals by Wet Ball Milling.

ABSTRACT: Lead halide perovskites of APbX₃ type [A = Cs, formamidinium (FA), methylammonium; X = Br, I] in the form of ligand-capped colloidal nanocrystals (NCs) are widely studied as versatile photonic sources. FAPbBr₃ and CsPbBr₃ NCs have become promising as spectrally narrow green primary emitters in backlighting of liquid-crystal displays (peak at 520-530 nm, full width at half-maximum of 22-30 nm). Herein, we report that wet ball milling of bulk APbBr₃ (A = Cs, FA) mixed with solvents and capping ligands yields green luminescent colloidal NCs with a high overall reaction yield and optoelectronic quality on par with that of NCs of the same composition obtained by hot-injection method. We emphasize the superiority of oleylammonium bromide as a capping ligand used for this procedure over the standard oleic acid and oleylamine. We also show a mechanically induced anion-exchange reaction for the formation of orange-emissive CsPb(Br/I)₃ NCs.

SUBMITTER: Protesescu L

PROVIDER: S-EPMC5999230 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature

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Low-Cost Synthesis of Highly Luminescent Colloidal Lead Halide Perovskite Nanocrystals by Wet Ball Milling.

Protesescu Loredana L Yakunin Sergii S Nazarenko Olga O Dirin Dmitry N DN Kovalenko Maksym V MV

ACS applied nano materials 20180305 3

Lead halide perovskites of APbX3 type [A = Cs, formamidinium (FA), methylammonium; X = Br, I] in the form of ligand-capped colloidal nanocrystals (NCs) are widely studied as versatile photonic sources. FAPbBr3 and CsPbBr3 NCs have become promising as spectrally narrow green primary emitters in backlighting of liquid-crystal displays (peak at 520-530 nm, full width at half-maximum of 22-30 nm). Herein, we report that wet ball milling of bulk APbBr3 (A = ...[more]

PMID: 29911683

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Project description:Hybrid organic-inorganic and fully inorganic lead halide perovskite nanocrystals (NCs) have recently emerged as versatile solution-processable light-emitting and light-harvesting optoelectronic materials. A particularly difficult challenge lies in warranting the practical utility of such semiconductor NCs in the red and infrared spectral regions. In this context, all three archetypal A-site monocationic perovskites-CH3NH3PbI3, CH(NH2)2PbI3, and CsPbI3-suffer from either chemical or thermodynamic instabilities in their bulk form. A promising approach toward the mitigation of these challenges lies in the formation of multinary compositions (mixed cation and mixed anion). In the case of multinary colloidal NCs, such as quinary Cs xFA1- xPb(Br1- yI y)3 NCs, the outcome of the synthesis is defined by a complex interplay between the bulk thermodynamics of the solid solutions, crystal surface energies, energetics, dynamics of capping ligands, and the multiple effects of the reagents in solution. Accordingly, the rational synthesis of such NCs is a formidable challenge. Herein, we show that droplet-based microfluidics can successfully tackle this problem and synthesize Cs xFA1- xPbI3 and Cs xFA1- xPb(Br1- yI y)3 NCs in both a time- and cost-efficient manner. Rapid in situ photoluminescence and absorption measurements allow for thorough parametric screening, thereby permitting precise optical engineering of these NCs. In this showcase study, we fine-tune the photoluminescence maxima of such multinary NCs between 700 and 800 nm, minimize their emission line widths (to below 40 nm), and maximize their photoluminescence quantum efficiencies (up to 89%) and phase/chemical stabilities. Detailed structural analysis revealed that the Cs xFA1- xPb(Br1- yI y)3 NCs adopt a cubic perovskite structure of FAPbI3, with iodide anions partially substituted by bromide ions. Most importantly, we demonstrate the excellent transference of reaction parameters from microfluidics to a conventional flask-based environment, thereby enabling up-scaling and further implementation in optoelectronic devices. As an example, Cs xFA1- xPb(Br1- yI y)3 NCs with an emission maximum at 735 nm were integrated into light-emitting diodes, exhibiting a high external quantum efficiency of 5.9% and a very narrow electroluminescence spectral bandwidth of 27 nm.

Dataset Information

Low-Cost Synthesis of Highly Luminescent Colloidal Lead Halide Perovskite Nanocrystals by Wet Ball Milling.

Publications

Low-Cost Synthesis of Highly Luminescent Colloidal Lead Halide Perovskite Nanocrystals by Wet Ball Milling.

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