Interfacial Self-Assembly and Oriented Attachment in the Family of PbX (X = S, Se, Te) Nanocrystals.

ABSTRACT: The realization of materials with new optoelectronic properties draws much scientific attention toward the field of nanocrystal superstructures. Low-dimensional superstructures created by interfacial assembly and oriented attachment of PbSe nanocrystals are a striking example because theory showed that PbSe sheets with a honeycomb geometry possess non-trivial flat bands and Dirac cones in the valence and conduction bands. Here, we report on the formation of one-dimensional linear and zigzag structures and two-dimensional (2D) square and honeycomb structures for the entire lead chalcogenide family: PbX (X = S, Se, Te). We observe that PbTe, with a lower bulk melting temperature and enthalpy of formation than those of PbSe, shows a higher nanocrystal surface reactivity, such that the surface

SUBMITTER: van Overbeek C 

PROVIDER: S-EPMC6004561 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature