A practical guide for using lithium halocarbenoids in homologation reactions.
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ABSTRACT: Abstract
Lithium halocarbenoids are versatile reagents for accomplishing homologation processes. The fast ?-elimination they suffer has been considered an important limitation for their extensive use. Herein, we present a series of practical considerations for an effective employment in the homologation of selected carbon electrophiles.Graphical abstract
SUBMITTER: Monticelli S
PROVIDER: S-EPMC6006224 | biostudies-literature | 2018
REPOSITORIES: biostudies-literature
Publications
A practical guide for using lithium halocarbenoids in homologation reactions.
Monticelli Serena S Rui Marta M Castoldi Laura L Missere Giada G Pace Vittorio V
Monatshefte fur chemie 20180611 7
<h4>Abstract</h4>Lithium halocarbenoids are versatile reagents for accomplishing homologation processes. The fast α-elimination they suffer has been considered an important limitation for their extensive use. Herein, we present a series of practical considerations for an effective employment in the homologation of selected carbon electrophiles.<h4>Graphical abstract</h4> ...[more]
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