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A "roller-wheel" Pt-containing small molecule that outperforms its polymer analogs in organic solar cells.

ABSTRACT: A novel Pt-bisacetylide small molecule (Pt-SM) featuring "roller-wheel" geometry was synthesized and characterized. When compared with conventional Pt-containing polymers and small molecules having "dumbbell" shaped structures, Pt-SM displays enhanced crystallinity and intermolecular ?-? interactions, as well as favorable panchromatic absorption behaviors. Organic solar cells (OSCs) employing Pt-SM achieve power conversion efficiencies (PCEs) up to 5.9%, the highest reported so far for Pt-containing polymers and small molecules.

SUBMITTER: He W

PROVIDER: S-EPMC6021780 | biostudies-literature | 2016 Sep

REPOSITORIES: biostudies-literature

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A "roller-wheel" Pt-containing small molecule that outperforms its polymer analogs in organic solar cells.

He Wenhan W Livshits Maksim Y MY Dickie Diane A DA Yang Jianzhong J Quinnett Rachel R Rack Jeffrey J JJ Wu Qin Q Qin Yang Y

Chemical science 20160523 9

A novel Pt-bisacetylide small molecule (Pt-SM) featuring "roller-wheel" geometry was synthesized and characterized. When compared with conventional Pt-containing polymers and small molecules having "dumbbell" shaped structures, Pt-SM displays enhanced crystallinity and intermolecular π-π interactions, as well as favorable panchromatic absorption behaviors. Organic solar cells (OSCs) employing Pt-SM achieve power conversion efficiencies (PCEs) up to 5.9%, the highest reported ...[more]

PMID: 30034718

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