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An Electrochemical Study on the Copolymer Formed from Piperazine and Aniline Monomers.

ABSTRACT: A study on the electrochemical oxidation of piperazine and its electrochemical copolymerization with aniline in acidic medium is presented. It was found that the homopolymerization of piperazine cannot be achieved under electrochemical conditions. A combination of electrochemistry, in situ Fourier transform infrared (FTIR), and ex situ X-ray photoelectron spectroscopy (XPS) spectroscopies was used to characterize both the chemical structure and the redox behavior of an electrochemically synthesized piperazine?aniline copolymer. The electrochemical sensing properties of the deposited material were also tested against ascorbic acid and dopamine as redox probes.

SUBMITTER: Dkhili S

PROVIDER: S-EPMC6025326 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature

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An Electrochemical Study on the Copolymer Formed from Piperazine and Aniline Monomers.

Dkhili Samiha S López-Bernabeu Sara S Kedir Chahineze Nawel CN Huerta Francisco F Montilla Francisco F Besbes-Hentati Salma S Morallon Emilia E

Materials (Basel, Switzerland) 20180614 6

A study on the electrochemical oxidation of piperazine and its electrochemical copolymerization with aniline in acidic medium is presented. It was found that the homopolymerization of piperazine cannot be achieved under electrochemical conditions. A combination of electrochemistry, in situ Fourier transform infrared (FTIR), and ex situ X-ray photoelectron spectroscopy (XPS) spectroscopies was used to characterize both the chemical structure and the redox behavior of an electrochemically synthesi ...[more]

PMID: 29904009

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