Ontology highlight
ABSTRACT:
SUBMITTER: Martinez-Calvo M
PROVIDER: S-EPMC6038097 | biostudies-literature | 2018 Jul
REPOSITORIES: biostudies-literature
Martínez-Calvo Miguel M Couceiro José R JR Destito Paolo P Rodríguez Jéssica J Mosquera Jesús J Mascareñas José L JL
ACS catalysis 20180601 7
Discrete palladium(II) complexes featuring purposely designed phosphine ligands can promote depropargylation and deallylation reactions in cell lysates. These complexes perform better than other palladium sources, which apparently are rapidly deactivated in such hostile complex media. This good balance between reactivity and stability allows the use of these discrete phosphine palladium complexes in living mammalian cells, whereby they can mediate similar transformations. The presence of a phosp ...[more]