High-Performing Biodegradable Waterborne Polyester/Functionalized Graphene Oxide Nanocomposites as an Eco-Friendly Material.

ABSTRACT: The development of high-performing nanocomposites of homogeneously dispersed graphene oxide in a waterborne polyester matrix with controlled interfacial interactions is a daunting challenge owing to the presence of strong cohesive energy in both. Thus, in this study, graphene oxide was functionalized with toluene diisocyanate and butane diol through a simple method and incorporated into the waterborne polyester matrix through a facile in situ bulk polymerization technique without using any compatibilizing agent or organic solvent for the first time. The thermoset of the nanocomposite was formed by curing it with hyperbranched epoxy of glycerol and poly(amido amine). The resultant thermosetting nanocomposites with 0.1-1 wt % functionalized graphene oxide exhibited significant enhancement in mechanical properties such as elongation at break (245-360%), tensile strength (7.8-39.4 MPa), scratch hardness (4 to >10 kg), toughness (17.18-86.35 MJ/m3), Young's modulus (243-358 MPa), impact resistance (8.3 to >9.3 kJ/m), and thermostability. Further, the Halpin-Tsai model was used to predict the alignment of graphene oxide. The nanocomposite was also biodegradable against the Pseudomonas aeruginosa bacterial strain. Furthermore, this nanocomposite exhibited strong catalytic activity for the aza-Michael addition reaction. Thus, the nanocomposite can be utilized as a high-performing sustainable material in different potential applications including as heterogeneous catalysts.

SUBMITTER: Hazarika D 

PROVIDER: S-EPMC6044861 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature