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Highly Active and Stable CH4 Oxidation by Substitution of Ce4+ by Two Pd2+ Ions in CeO2(111).


ABSTRACT: Methane (CH4) combustion is an increasingly important reaction for environmental protection, for which Pd/CeO2 has emerged as the preferred catalyst. There is a lack of understanding of the nature of the active site in these catalysts. Here, we use density functional theory to understand the role of doping of Pd in the ceria surface for generating sites highly active toward the C-H bonds in CH4. Specifically, we demonstrate that two Pd2+ ions can substitute one Ce4+ ion, resulting in a very stable structure containing a highly coordinated unsaturated Pd cation that can strongly adsorb CH4 and dissociate the first C-H bond with a low energy barrier. An important aspect of the high activity of the stabilized isolated Pd cation is its ability to form a strong ?-complex with CH4, which leads to effective activation of CH4. We show that also other transition metals like Pt, Rh, and Ni can give rise to similar structures with high activity toward C-H bond dissociation. These insights provide us with a novel structural view of solid solutions of transition metals such as Pt, Pd, Ni, and Rh in CeO2, known to exhibit high activity in CH4 combustion.

SUBMITTER: Su YQ 

PROVIDER: S-EPMC6046217 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature

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Highly Active and Stable CH<sub>4</sub> Oxidation by Substitution of Ce<sup>4+</sup> by Two Pd<sup>2+</sup> Ions in CeO<sub>2</sub>(111).

Su Ya-Qiong YQ   Liu Jin-Xun JX   Filot Ivo A W IAW   Zhang Long L   Hensen Emiel J M EJM  

ACS catalysis 20180606 7


Methane (CH<sub>4</sub>) combustion is an increasingly important reaction for environmental protection, for which Pd/CeO<sub>2</sub> has emerged as the preferred catalyst. There is a lack of understanding of the nature of the active site in these catalysts. Here, we use density functional theory to understand the role of doping of Pd in the ceria surface for generating sites highly active toward the C-H bonds in CH<sub>4</sub>. Specifically, we demonstrate that two Pd<sup>2+</sup> ions can subst  ...[more]

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