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Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor.

ABSTRACT: Synthesis of two dimensional (2D) materials mainly relies on interface-templates, exfoliation of layered crystals and surfactant-assistance. Here we have realized another strategy of polymerization in a 2D nano-reactor. As an application of this strategy, a 2D nano-reactor was constructed within a new pillar-layer metal organic framework (MOF) and in this nano-reactor a moderately stable 2D phosphorus material was synthesized from white phosphorus (P₄). Our research may provide a new approach for the synthesis of various 2D materials.

SUBMITTER: Li M

PROVIDER: S-EPMC6050534 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature

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Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor.

Li Ming M Ma Chuang C Liu Xiong X Su Jun J Cui Xiaofeng X He Yunbin Y

Chemical science 20180612 27

Synthesis of two dimensional (2D) materials mainly relies on interface-templates, exfoliation of layered crystals and surfactant-assistance. Here we have realized another strategy of polymerization in a 2D nano-reactor. As an application of this strategy, a 2D nano-reactor was constructed within a new pillar-layer metal organic framework (MOF) and in this nano-reactor a moderately stable 2D phosphorus material was synthesized from white phosphorus (P<sub>4</sub>). Our research may provide a new ...[more]

PMID: 30079205

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