Uranium and thorium complexes of the phosphaethynolate ion.
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ABSTRACT:
SUBMITTER: Camp C
PROVIDER: S-EPMC6054101 | biostudies-literature | 2015 Nov
REPOSITORIES: biostudies-literature
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Uranium and thorium complexes of the phosphaethynolate ion.
Camp Clément C Settineri Nicholas N Lefèvre Julia J Jupp Andrew R AR Goicoechea José M JM Maron Laurent L Arnold John J
Chemical science 20150720 11
New <i>tris</i>-amidinate actinide (Th, U) complexes containing a rare O-bound terminal phosphaethynolate (OCP <sup><b>-</b></sup> ) ligand were synthesized and fully characterized. The cyanate (OCN <sup><b>-</b></sup> ) and thiocyanate (SCN <sup><b>-</b></sup> ) analogs were prepared for comparison and feature a preferential N-coordination to the actinide metals. The Th(amid)<sub>3</sub>(OCP) complex reacts with Ni(COD)<sub>2</sub> to yield the heterobimetallic adduct (amid) <sub><b>3</b></sub> ...[more]
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