On-Surface Bottom-Up Synthesis of Azine Derivatives Displaying Strong Acceptor Behavior.

ABSTRACT: On-surface synthesis is an emerging approach to obtain, in a single step, precisely defined chemical species that cannot be obtained by other synthetic routes. The control of the electronic structure of organic/metal interfaces is crucial for defining the performance of many optoelectronic devices. A facile on-surface chemistry route has now been used to synthesize the strong electron-acceptor organic molecule quinoneazine directly on a Cu(110) surface, via thermally activated covalent coupling of para-aminophenol precursors. The mechanism is described using a combination of in situ surface characterization techniques and theoretical methods. Owing to a strong surface-molecule interaction, the quinoneazine molecule accommodates 1.2 electrons at its carbonyl ends, inducing an intramolecular

SUBMITTER: Ruiz Del Arbol N 

PROVIDER: S-EPMC6055674 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature