Synthesis of Porous CoFe?O? and Its Application as a Peroxidase Mimetic for Colorimetric Detection of H?O? and Organic Pollutant Degradation.

ABSTRACT: Porous CoFe?O? was prepared via a simple and controllable method to develop a low-cost, high-efficiency, and good-stability nanozyme. The morphology and microstructure of the obtained CoFe?O? was investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), specific surface area and pore analysis, and Raman spectroscopy. The results show that the annealing temperature has an important effect on the crystallinity, grain size, and specific surface area of CoFe?O?. CoFe?O? obtained at 300 °C (CF300) exhibits the largest surface area (up to 204.1 m² g⁻¹) and the smallest grain size. The peroxidase-like activity of CoFe?O? was further verified based on the oxidation of peroxidase substrate 3,3’,5,5’-tetramethylbenzidine (TMB) in the presence of H?O?. The best peroxidase-like activity for CF300 should be ascribed to its largest surface area and smallest grain size. On this basis, an effective method of colorimetric detection H?O? was established. In addition, the porous CoFe?O? was also used for the catalytic oxidation of methylene blue (MB), indicating potential applications in pollutant removal and water treatment.

SUBMITTER: Wu L 

PROVIDER: S-EPMC6071025 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature