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Crystal structure of N-allyl-4-methyl-benzene-sulfonamide.

ABSTRACT: The title compound, C10H13NO2S, was synthesized by a nucleophilic substitution reaction between allyl amine and p-toluene-sulfonyl chloride. The sulfonate S-O bond lengths are 1.4282 (17) and 1.4353 (17) Å, and the C-N-S-C torsion angle involving the sulfonamide moiety is -61.0 (2)°. In the crystal, centrosymmetric dimers of the title compound are present via inter-molecular N-H⋯O hydrogen bonds between sulfonamide groups. These dimers are linked into ribbons along the c-axis direction through offset π-π inter-actions.

SUBMITTER: Patel ZS

PROVIDER: S-EPMC6072992 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature

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Crystal structure of N-allyl-4-methyl-benzene-sulfonamide.

Patel Zeel S ZS Stevens Amanda C AC Bookout Erin C EC Staples Richard J RJ Biros Shannon M SM Ngassa Felix N FN

Acta crystallographica. Section E, Crystallographic communications 20180720 Pt 8

The title compound, C10H13NO2S, was synthesized by a nucleophilic substitution reaction between allyl amine and p-toluene-sulfonyl chloride. The sulfonate S-O bond lengths are 1.4282 (17) and 1.4353 (17) Å, and the C-N-S-C torsion angle involving the sulfonamide moiety is -61.0 (2)°. In the crystal, centrosymmetric dimers of the title compound are present via inter-molecular N-H⋯O hydrogen bonds between sulfonamide groups. These dimers are linked in ...[more]

PMID: 30116576

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