Ontology highlight
ABSTRACT:
SUBMITTER: Spitzer F
PROVIDER: S-EPMC6099418 | biostudies-literature | 2018 Jul
REPOSITORIES: biostudies-literature
Spitzer Fabian F Balázs Gábor G Graßl Christian C Keilwerth Martin M Meyer Karsten K Scheer Manfred M
Angewandte Chemie (International ed. in English) 20180608 28
In a systematic study of the activation of As<sub>4</sub> , three [LCo(tol)] (L=β-diiminato) complexes have revealed different steric and electronic influences. 2,6-Diisopropylphenyl (Dipp) and 2,6-dimethylphenyl (dmp) flanking groups were used, one of the ligands with H backbone substituents (β-dialdiminate L<sup>0</sup> ) and two with Me substituents (β-diketiminates L<sup>3</sup> and L<sup>1</sup> ). In the reaction with As<sub>4</sub> , different dinuclear products [(LCo)<sub>2</sub> As<sub> ...[more]