Ontology highlight
ABSTRACT:
SUBMITTER: Gahtory D
PROVIDER: S-EPMC6099469 | biostudies-literature | 2018 Aug
REPOSITORIES: biostudies-literature
Gahtory Digvijay D Sen Rickdeb R Kuzmyn Andriy R AR Escorihuela Jorge J Zuilhof Han H
Angewandte Chemie (International ed. in English) 20180417 32
Novel click reactions are of continued interest in fields as diverse as bio-conjugation, polymer science and surface chemistry. Qualification as a proper "click" reaction requires stringent criteria, including fast kinetics and high conversion, to be met. Herein, we report a novel strain-promoted cycloaddition between cyclopropenes and o-quinones in solution and on a surface. We demonstrate the "click character" of the reaction in solution and on surfaces for both monolayer and polymer brush fun ...[more]