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Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions.

ABSTRACT: Novel complexes of 1,2-P,N-bidentate ferrocenyl ligands with AgOAc or with [RuCl?(PPh?)?] as catalysts have been studied in asymmetric synthesis. The catalytic activity of these systems have been studied in [3+2]-cycloaddition of azomethine ylides with olefins and the asymmetric transfer hydrogenation of ketones.

SUBMITTER: Utepova IA 

PROVIDER: S-EPMC6100496 | biostudies-literature | 2018 May

REPOSITORIES: biostudies-literature

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Enantiomerically Enriched 1,2-<i>P</i>,<i>N</i>-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions.

Utepova Irina A IA   Serebrennikova Polina O PO   Streltsova Marina S MS   Musikhina Alexandra A AA   Fedorchenko Tatiana G TG   Chupakhin Oleg N ON   Antonchick Andrey P AP  

Molecules (Basel, Switzerland) 20180530 6

Novel complexes of 1,2-<i>P</i>,<i>N</i>-bidentate ferrocenyl ligands with AgOAc or with [RuCl₂(PPh₃)₃] as catalysts have been studied in asymmetric synthesis. The catalytic activity of these systems have been studied in [3+2]-cycloaddition of azomethine ylides with olefins and the asymmetric transfer hydrogenation of ketones. ...[more]

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