Ontology highlight
ABSTRACT:
SUBMITTER: Brown AC
PROVIDER: S-EPMC6102661 | biostudies-literature | 2017 Jul
REPOSITORIES: biostudies-literature
Brown Alexandra C AC Altman Alison B AB Lohrey Trevor D TD Hohloch Stephan S Arnold John J
Chemical science 20170531 7
We report the synthesis and reactivity of paramagnetic heterometallic complexes containing a Ti(iii)-μ-H-Al(iii) moiety. Combining different stoichiometries amounts of Cp<sub>2</sub>TiCl and KH<sub>3</sub>AlC(TMS)<sub>3</sub> (Cp = cyclopentadienyl, TMS = trimethylsilyl) resulted in the formation of either bimetallic Cp<sub>2</sub>Ti(μ-H)<sub>2</sub>(H)AlC(TMS)<sub>3</sub> (<b>2</b>) or trimetallic (Cp<sub>2</sub>Ti)<sub>2</sub>(μ-H)<sub>3</sub>(H)AlC(TMS)<sub>3</sub> (<b>3</b>) <i>via</i> salt ...[more]