Unknown

Dataset Information

0

Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity.


ABSTRACT: The design of molecular complexes of earth-abundant first-row transition metals that can catalyze multi-electron C-H bond activation processes is of interest for achieving efficient, low-cost syntheses of target molecules. To overcome the propensity of these metals to perform single-electron processes, redox-active ligands have been utilized to provide additional electron equivalents. Herein, we report the synthesis of a novel redox active ligand, [ibaps]3-, which binds to transition metals such as FeII and CoII in a meridional fashion through the three anionic nitrogen atoms and provides additional coordination sites for other ligands. In this study, the neutral bidentate ligand 2,2'-bipyridine (bpy) was used to complete the coordination spheres of the metal ions and form NEt4[MII(ibaps)bpy] (M = Fe (1) or Co (1-Co)) salts. The FeII salt exhibited rich electrochemical properties and could be chemically oxidized by 1 and 2 equiv. of ferrocenium to form singly and doubly oxidized species, respectively. The reactivity of 1 towards intramolecular C-H bond amination of aryl azides at benzylic and aliphatic carbon centers was explored, and moderate to good yields of the resulting indoline products were obtained.

SUBMITTER: Cook SA 

PROVIDER: S-EPMC6115676 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC8324332 | biostudies-literature
| S-EPMC4679572 | biostudies-literature
| S-EPMC3954711 | biostudies-literature
| S-EPMC2593863 | biostudies-literature
| S-EPMC4236838 | biostudies-literature
| S-EPMC6862439 | biostudies-literature
| S-EPMC6165629 | biostudies-literature
| S-EPMC6506801 | biostudies-literature
| S-EPMC4215643 | biostudies-literature
| S-EPMC6337720 | biostudies-literature