The Pentagonal-Pyramidal Hexamethylbenzene Dication: Many Shades of Coordination Chemistry at Carbon.

ABSTRACT: A recent report on the crystal structure of the pentagonal-pyramidal hexamethylbenzene dication C₆ (CH₃ )₆²⁺ by Malischewski and Seppelt [Angew. Chem. Int. Ed. 2017, 56, 368] confirmed the structural proposal made in the first report of this compound in 1973 by Hogeveen and Kwant [Tetrahedron Lett. 1973, 14, 1665]. The widespread attention that this compound quickly gained led us to reinvestigate its electronic structure. On the basis of intrinsic bond orbital analysis, effective oxidation state analysis, ring current analysis, and comparison with well-established coordination complexes, it is demonstrated that the central carbon atom behaves like a transition metal. The central (apical) carbon atom, although best described as a highly Lewis-acid

SUBMITTER: Klein JEMN 

PROVIDER: S-EPMC6120489 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature