Ontology highlight
ABSTRACT:
SUBMITTER: Guan H
PROVIDER: S-EPMC6122274 | biostudies-literature | 2018
REPOSITORIES: biostudies-literature
Guan Haiyan H Zhou Mingbo M Yin Bangshao B Xu Ling L Song Jianxin J
Beilstein journal of organic chemistry 20180730
A π-extended "earring" subporphyrin <b>3</b> was synthesized from β,β'-diiodosubporphyrin and diboryltripyrrane via a Suzuki-Miyaura coupling and following oxidation. Its Pd complex <b>3Pd</b> was also synthesized and both of the compounds were fully characterized by <sup>1</sup>H NMR, MS and X-ray single crystal diffraction. The <sup>1</sup>H NMR spectra and single crystal structures revealed that aromatic ring current did not extend to the "ear" in both of the two compounds. Their UV-vis/NIR s ...[more]