Ontology highlight
ABSTRACT:
SUBMITTER: Zheng XL
PROVIDER: S-EPMC6122368 | biostudies-literature | 2018
REPOSITORIES: biostudies-literature
Beilstein journal of organic chemistry 20180808
A novel functional [2]rotaxane containing two alkenyl bonds was designed, synthesized and characterized by <sup>1</sup>H, <sup>13</sup>C NMR spectroscopy and HRESI mass spectrometry. The introduction of alkenyl bonds endowed the [2]rotaxane a fascinating ability to react with versatile functional groups such as alkenyl and thiol functional groups. The reversible shuttling movement of the macrocycle between two different recognition sites on the molecular thread can be driven by external acid and ...[more]