Unknown

Dataset Information

0

Synthesis of 5-Methylene-2-pyrrolones.

ABSTRACT: A facile, one-pot synthetic method for the synthesis of 5-methylene-2-pyrrolones (5MPs) from inexpensive furfuryl acetate is described. Bromine oxidation and trapping of the in situ generated 1,4-dicarbonyl compound by a primary amine provided the corresponding 5MPs in 50-69% yield.

SUBMITTER: Jacinto MP 

PROVIDER: S-EPMC6132240 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Synthesis of 5-Methylene-2-pyrrolones.

Jacinto Marco Paolo MP   Pichling Patricio P   Greenberg Marc M MM  

Organic letters 20180731 16

A facile, one-pot synthetic method for the synthesis of 5-methylene-2-pyrrolones (5MPs) from inexpensive furfuryl acetate is described. Bromine oxidation and trapping of the in situ generated 1,4-dicarbonyl compound by a primary amine provided the corresponding 5MPs in 50-69% yield. ...[more]

Similar Datasets

Unknown Thiol Specific and Tracelessly Removable Bioconjugation via Michael Addition to 5-Methylene Pyrrolones.
| S-EPMC5491101 | biostudies-literature
Unknown Cysteine-specific protein multi-functionalization and disulfide bridging using 3-bromo-5-methylene pyrrolones.
| S-EPMC7035330 | biostudies-literature
Unknown Pt-catalyzed cyclization/1,2-migration for the synthesis of indolizines, pyrrolones, and indolizinones.
| S-EPMC3384527 | biostudies-other
Unknown Organocatalytic Synthesis of Methylene-Bridged N-Heterobiaryls.
| S-EPMC5148643 | biostudies-literature
Unknown Pt-catalyzed cyclization/migration of propargylic alcohols for the synthesis of 3(2H)-furanones, pyrrolones, indolizines, and indolizinones.
| S-EPMC3351138 | biostudies-literature
Unknown Pyran annulation: asymmetric synthesis of 2,6-disubstituted-4-methylene tetrahydropyrans.
| S-EPMC1480410 | biostudies-literature
Unknown Synthesis of TiO2NWS@AuNPS Composite Catalyst for Methylene Blue Removal.
| S-EPMC6025176 | biostudies-literature
Unknown Bifurcated synthesis of methylene-lactone- and methylene-lactam-fused spirolactams via electrophilic amide allylation of γ-phenylthio-functionalized γ-lactams.
| S-EPMC7670114 | biostudies-literature
Unknown Synthesis of activated carbon from biowaste of fir bark for methylene blue removal.
| S-EPMC6774956 | biostudies-literature
Unknown Functionalized Attapulgite for the Adsorption of Methylene Blue: Synthesis, Characterization, and Adsorption Mechanism.
| S-EPMC8340108 | biostudies-literature