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Catalytic aziridination with alcoholic substrates via a chromium tetracarbene catalyst.

ABSTRACT: The first examples of aziridination catalysis with a chromium complex are communicated. This tetracarbene chromium complex provides novel catalytic aziridination reactions with protic substrates such as alcohols or amines on the alkene or organic azide and is the most effective catalyst at low alkene loading for aliphatic alkenes to date.

SUBMITTER: Keller CL

PROVIDER: S-EPMC6136250 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

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Catalytic aziridination with alcoholic substrates via a chromium tetracarbene catalyst.

Keller C Luke CL Kern Jesse L JL Terry Bradley D BD Roy Sharani S Jenkins David M DM

Chemical communications (Cambridge, England) 20180104 12

The first examples of aziridination catalysis with a chromium complex are communicated. This tetracarbene chromium complex provides novel catalytic aziridination reactions with protic substrates such as alcohols or amines on the alkene or organic azide and is the most effective catalyst at low alkene loading for aliphatic alkenes to date. ...[more]

PMID: 29299550

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