Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Base-Resistant Ionic Metal-Organic Framework as a Porous Ion-Exchange Sorbent.

ABSTRACT: A systematic approach has been employed to obtain a hydrolytically stable cationic metal-organic framework (MOF). The synthesized two-dimensional Ni(II)-centered cationic MOF, having its backbone built from purely neutral N-donor ligand, is found to exhibit uncommon resistance over wide pH range, particularly even under highly alkaline conditions. This report presents a rare case of a porous MOF retaining structural integrity under basic conditions, and an even rarer case of a porous cationic MOF. The features of stability and porosity in this ionic MOF have been harnessed for the function of charge- and size-selective capture of small organic dye through ion-exchange process across a wide pH range.

SUBMITTER: Desai AV

PROVIDER: S-EPMC6137287 | biostudies-literature | 2018 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Base-Resistant Ionic Metal-Organic Framework as a Porous Ion-Exchange Sorbent.

Desai Aamod V AV Roy Arkendu A Samanta Partha P Manna Biplab B Ghosh Sujit K SK

iScience 20180412

A systematic approach has been employed to obtain a hydrolytically stable cationic metal-organic framework (MOF). The synthesized two-dimensional Ni(II)-centered cationic MOF, having its backbone built from purely neutral N-donor ligand, is found to exhibit uncommon resistance over wide pH range, particularly even under highly alkaline conditions. This report presents a rare case of a porous MOF retaining structural integrity under basic conditions, and an even rarer case of a porous cationic MO ...[more]

PMID: 30428321

Similar Datasets

Carbon dioxide capture and conversion by an acid-base resistant metal-organic framework.

Project description:Considering the rapid increase of CO2 emission, especially from power plants, there is a constant need for materials which can effectively eliminate post-combustion CO2 (the main component: CO2/N2?=?15/85). Here, we show the design and synthesis of a Cu(II) metal-organic framework (FJI-H14) with a high density of active sites, which displays unusual acid and base stability and high volumetric uptake (171?cm3?cm-3) of CO2 under ambient conditions (298?K, 1?atm), making it a potential adsorbing agent for post-combustion CO2. Moreover, CO2 from simulated post-combustion flue gas can be smoothly converted into corresponding cyclic carbonates by the FJI-H14 catalyst. Such high CO2 adsorption capacity and moderate catalytic activity may result from the synergistic effect of multiple active sites.

| S-EPMC5663901 | biostudies-other

Size control over metal-organic framework porous nanocrystals.

Project description:Porous nanocrystals of metal-organic frameworks (MOFs) offer greater bioavailability, higher surface-to-volume ratios, superior control over MOF membrane fabrication, and enhanced guest-sorption kinetics compared to analogous bulk phases, but reliable synthesis of uniformly sized particles remains an outstanding challenge. Here, we identify the smallest and most probable sizes of known MOF nanocrystals and present an exhaustive comparative summary of nano- versus bulk-MOF syntheses. Based on critical analysis of reported size data and experimental conditions, an alternate to the LaMer model is proposed that describes nanocrystal formation as a kinetic competition between acid-base and metal-ligand reactivity. Particle growth terminates when ligands outcompete metal-ion diffusion, thereby arresting polymerization to produce kinetically trapped particle sizes. This model reconciles disparate trends in the literature and postulates that minimum particle sizes can be achieved by minimizing the relative ratios of metal-to-linker local concentrations. By identifying conditions that disfavor small nanocrystal sizes, this model also provides routes towards macroscopic MOF single crystals. A universal "seesaw" relationship between nanocrystal sizes and the concentrations of acidic surface-capping ligands provides a roadmap for achieving precise synthetic control. Best practices in synthesis, characterization, and data presentation are recommended for future investigations so that MOF nanocrystals may achieve their full potential as advanced nanomaterials.

| S-EPMC6979335 | biostudies-literature

High-Performance Metal-Organic Framework-Templated Sorbent for Selective Eu(III) Capture.

Project description:A stable porous sorbent M1 was achieved through the specific transformation of flexible thioalkyl groups and metal cluster sites in a zirconium MOF (metal-organic framework; Zr-L) template. The target polymer combines sulfoxide/sulfone and phosphoric acid in a single framework, which was fully characterized by 1H-NMR, PXRD, IR, and elemental analysis. When employed as the heavy metal adsorbent, M1 exhibit a remarkable Eu(III) sorption behavior, achieving both high chemical affinity (K d = 105) and sorption capacity (the maximum Eu(III) sorption capacity reached 220 mg g-1 at pH = 4.0 and T = 298 K calculated from the Langmuir model). Recyclability and selectivity test of M1 further prove that the sorbent is highly stable and effective for europium enrichment in the aqueous solution. This work takes focus on the introduction of multifunctional groups into a single polymeric framework in a feasible and environmentally friendly way and highlights the sorption efficiency for europium removal from the aqueous solution.

| S-EPMC7144142 | biostudies-literature

Low temperature ionic conductor: ionic liquid incorporated within a metal-organic framework.

Project description:Ionic liquids (ILs) show promise as safe electrolytes for electrochemical devices. However, the conductivity of ILs decreases markedly at low temperatures because of strong interactions arising between the component ions. Metal-organic frameworks (MOFs) are appropriate microporous host materials that can control the dynamics of ILs via the nanosizing of ILs and tunable interactions of MOFs with the guest ILs. Here, for the first time, we report on the ionic conductivity of an IL incorporated within a MOF. The system studied consisted of EMI-TFSA (1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide) and ZIF-8 (Zn(MeIM)2, H(MeIM) = 2-methylimidazole) as the IL and the MOF, respectively. While the ionic conductivity of bulk EMI-TFSA showed a sharp decrease arising from freezing, the EMI-TFSA@ZIF-8 showed no marked decrease because there was no phase transition. The ionic conductivity of EMI-TFSA@ZIF-8 was higher than that of bulk EMI-TFSA below 250 K. This result points towards a novel method by which to design electrolytes for electrochemical devices such as batteries that can operate at low temperatures.

| S-EPMC5707510 | biostudies-literature

Solid state organic amine detection in a photochromic porous metal organic framework.

Project description:A new Mg(ii) based photochromic porous metal-organic framework (MOF) has been synthesized bearing naphthalenediimide (NDI) chromophoric unit. This MOF (Mg-NDI) shows instant and reversible solvatochromic behavior in presence of solvents with different polarity. Mg-NDI also exhibits fast and reversible photochromism via radical formation. Due to the presence of electron deficient NDI moiety, this MOF exhibits selective organic amine (electron rich) sensing in solid state. The organic amine detection has been confirmed by photoluminescence quenching experiment and visual color change.

| S-EPMC5811159 | biostudies-literature

A porous, electrically conductive hexa-zirconium(iv) metal-organic framework.

Project description:Engendering electrical conductivity in high-porosity metal-organic frameworks (MOFs) promises to unlock the full potential of MOFs for electrical energy storage, electrocatalysis, or integration of MOFs with conventional electronic materials. Here we report that a porous zirconium-node-containing MOF, NU-901, can be rendered electronically conductive by physically encapsulating C60, an excellent electron acceptor, within a fraction (ca. 60%) of the diamond-shaped cavities of the MOF. The cavities are defined by node-connected tetra-phenyl-carboxylated pyrene linkers, i.e. species that are excellent electron donors. The bulk electrical conductivity of the MOF is shown to increase from immeasurably low to 10-3 S cm-1, following fullerene incorporation. The observed conductivity originates from electron donor-acceptor interactions, i.e. charge-transfer interactions - a conclusion that is supported by density functional theory calculations and by the observation of a charge-transfer-derived band in the electronic absorption spectrum of the hybrid material. Notably, the conductive version of the MOF retains substantial nanoscale porosity and continues to display a sizable internal surface area, suggesting potential future applications that capitalize on the ability of the material to sorb molecular species.

| S-EPMC5956983 | biostudies-literature

Metal oxide decorated porous carbons from controlled calcination of a metal-organic framework.

Project description:Thermal decomposition of an iron-based MOF was conducted under controlled gas environments to understand the resulting porous carbon structure. Different phases and crystallite sizes of iron oxide are produced based on the specific gas species. In particular, air resulted in iron(iii) oxide, and D2O and CO2 resulted in the mixed valent iron(ii,iii) oxide. Performing the carbonization under non-oxidative or reducing conditions (N2, He, H2) resulted in the formation of a mixture of both iron(ii,iii) oxide and iron(iii) oxide. Based on in situ and air-free handling experiments, it was observed that this is partially due to the formation of zero-valent iron metal that is rapidly oxidized when exposed to air. Neutron pair distribution function analysis provided insight into the effect of the gas environment on the local structure of the porous carbon, indicating a noticeable change in local order between the D2O and the N2 calcined samples.

| S-EPMC9419259 | biostudies-literature

Transport of polymer-coated metal–organic framework nanoparticles in porous media

Project description:Injecting fluids into deep underground geologic structures is a critical component to development of long-term strategies for managing greenhouse gas emissions and facilitating energy extraction operations. Recently, we reported that metal–organic frameworks are low-frequency, absorptive-acoustic metamaterial that may be injected into the subsurface to enhance geophysical monitoring tools used to track fluids and map complex structures. A key requirement for this nanotechnology deployment is transportability through porous geologic media without being retained by mineral-fluid interfaces. We used flow-through column studies to estimate transport and retention properties of five different polymer-coated MIL-101(Cr) nanoparticles (NP) in siliceous porous media. When negatively charged polystyrene sulfonate coated nanoparticles (NP-PSS-70K) were transported in 1 M NaCl, only about 8.4% of nanoparticles were retained in the column. Nanoparticles coated with polyethylenimine (NP-PD1) exhibited significant retention (> 50%), emphasizing the importance of complex nanoparticle-fluid-rock interactions for successful use of nanofluid technologies in the subsurface. Nanoparticle transport experiments revealed that nanoparticle surface characteristics play a critical role in nanoparticle colloidal stability and as well the transport.

| S-EPMC9385709 | biostudies-literature

Studying manganese carbonyl photochemistry in a permanently porous metal-organic framework.

Project description:Mn(diimine)(CO)3X (X = halide) complexes are critical components of chromophores, photo- and electrocatalysts, and photoactive CO-releasing molecules (photoCORMs). While these entities have been incorporated into metal-organic frameworks (MOFs), a detailed understanding of the photochemical and chemical processes that occur in a permanently porous support is lacking. Here we site-isolate and study the photochemistry of a Mn(diimine)(CO)3Br moiety anchored within a permanently porous MOF support, allowing for not only the photo-liberation of CO from the metal but also its escape from the MOF crystals. In addition, the high crystallinity and structural flexibility of the MOF allows crystallographic snapshots of the photolysis products to be obtained. We report these photo-crystallographic studies in the presence of coordinating solvents, THF and acetonitrile, showing the changing coordination environment of the Mn species as CO loss proceeds. Using time resolved experiments, we report complementary spectroscopic studies of the photolysis chemistry and characterize the final photolysis product as a possible Mn(ii) entity. These studies inform the chemistry that occurs in MOF-based photoCORMs and where these moieties are employed as catalysts.

| S-EPMC10498678 | biostudies-literature

Ultrathin water-stable metal-organic framework membranes for ion separation.

Project description:Owing to the rich porosity and uniform pore size, metal-organic frameworks (MOFs) offer substantial advantages over other materials for the precise and fast membrane separation. However, achieving ultrathin water-stable MOF membranes remains a great challenge. Here, we first report the successful exfoliation of two-dimensional (2D) monolayer aluminum tetra-(4-carboxyphenyl) porphyrin framework (termed Al-MOF) nanosheets. Ultrathin water-stable Al-MOF membranes are assembled by using the exfoliated nanosheets as building blocks. While achieving a water flux of up to 2.2 mol m?2 hour?1 bar?1, the obtained 2D Al-MOF laminar membranes exhibit rejection rates of nearly 100% on investigated inorganic ions. The simulation results confirm that intrinsic nanopores of the Al-MOF nanosheets domain the ion/water separation, and the vertically aligned aperture channels are the main transport pathways for water molecules.

| S-EPMC7274808 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data