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ABSTRACT:
SUBMITTER: Mansikkamaki A
PROVIDER: S-EPMC6150729 | biostudies-literature | 2018 Jul
REPOSITORIES: biostudies-literature
Mansikkamäki Akseli A Tuononen Heikki M HM
The journal of physical chemistry letters 20180619 13
One of the first steps in designing ferromagnetic (FM) molecular materials of p-block radicals is the suppression of covalent radical-radical interactions that stabilize a diamagnetic ground state. In this contribution, we demonstrate that FM coupling between p-block radicals can be achieved by constructing mixed dimers from different radicals with differing symmetries of their singly occupied molecular orbitals. The applicability of this approach is demonstrated by studying magnetic interaction ...[more]