Ontology highlight
ABSTRACT:
SUBMITTER: Saura-Sanmartin A
PROVIDER: S-EPMC6152038 | biostudies-literature | 2017 Jun
REPOSITORIES: biostudies-literature
Saura-Sanmartin Adrian A Martinez-Espin Juan S JS Martinez-Cuezva Alberto A Alajarin Mateo M Berna Jose J
Molecules (Basel, Switzerland) 20170628 7
The synthesis of novel hydrogen-bonded [2]rotaxanes having two pyridine rings in the macrocycle and azo- and hydrazodicarboxamide-based templates decorated with four cyclohexyl groups is described. The different affinity of the binding sites for the benzylic amide macrocycle and the formation of programmed non-covalent interactions between the interlocked components have an important effect on the dynamic behavior of these compounds. Having this in mind, the chemical interconversion between the ...[more]