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Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under "On Water" Conditions.

ABSTRACT: We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)₂Zn] or [(PhSe)₂Zn]TMEDA with acyl chlorides under "on water" conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the presence of other functionalities in the starting material.

SUBMITTER: Sancineto L

PROVIDER: S-EPMC6152685 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature

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Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under "On Water" Conditions.

Sancineto Luca L Pinto Vargas Jaqueline J Monti Bonifacio B Arca Massimiliano M Lippolis Vito V Perin Gelson G Lenardao Eder Joao EJ Santi Claudio C

Molecules (Basel, Switzerland) 20170608 6

We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)₂Zn] or [(PhSe)₂Zn]TMEDA with acyl chlorides under "on water" conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the presence of other functionalities in the starting material. ...[more]

PMID: 28594361

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