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Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu?N@Ih-C80.

ABSTRACT: Photochemical carbosilylation of Lu?N@Ih-C80 was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts. Electrochemical studies indicated that the redox potentials of the carbosilylated derivatives were shifted cathodically in comparison with those of the [5,6]-pyrrolidino adducts. The electronic effect of the silirane addends on Lu?N@Ih-C80 was verified on the basis of density functional theory calculations.

SUBMITTER: Kako M

PROVIDER: S-EPMC6154294 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature

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Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu₃N@Ih-C80.

Kako Masahiro M Minami Kazuya K Kuroiwa Taiki T Fukazawa Shinpei S Arikawa Yuki Y Yamada Michio M Maeda Yutaka Y Li Qiao-Zhi QZ Nagase Shigeru S Akasaka Takeshi T

Molecules (Basel, Switzerland) 20170520 5

Photochemical carbosilylation of Lu₃N@Ih-C80 was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts. Electrochemical studies indicated that the redox potentials of the carbosilylated derivatives were shifted cathodically in comparison with those of the [5,6]-pyrrolidino adducts. The electronic effect of the silirane addends on Lu₃N@Ih-C80 was verified on the basis of density functional theor ...[more]

PMID: 28531116

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