Unknown

Dataset Information

0

The Impact of Cr3+ Doping on Temperature Sensitivity Modulation in Cr3+ Doped and Cr3+, Nd3+ Co-doped Y3Al5O12, Y3Al2Ga3O12, and Y3Ga5O12 Nanothermometers.


ABSTRACT: A new approach to enhance the sensitivity of transition metal ion based nanocrystalline luminescent thermometer is presented. It was shown that the increase of Cr3+ concentration in three types of garnet host namely Y3Al5O12, Y3Ga5O12, and Y3Al2Ga3O12 allows for significant enhancement of their performance in non-contact thermometry. This phenomenon is related to the weakening of the crystal field strength due to enlargement of average Cr3+-O2- distance at higher Cr3+ concentrations. By increasing Cr3+ concentration from 0.6 to 30%, the sensitivity increased by over one order of magnitude from S = 0.2%/°C to S = 2.2%/°C at 9°C in Y3Al2Ga3O12 nanocrystals. Moreover, it was found that due to the Cr3+ ? Nd3+ energy transfer in the Cr3+, Nd3+ co-doped system, the usable Cr3+ concentration, for which its emission can be detected, is limited to 10% while the sensitivity at -50°C was doubled (from 1.3%/°C for Y3Al2Ga3O12:10%Cr3+ to 2.2%/°C Y3Al2Ga3O12:10%Cr3+, 1%Nd3+ nanocrystals).

SUBMITTER: Elzbieciak K 

PROVIDER: S-EPMC6157326 | biostudies-literature | 2018

REPOSITORIES: biostudies-literature

altmetric image

Publications

The Impact of Cr<sup>3+</sup> Doping on Temperature Sensitivity Modulation in Cr<sup>3+</sup> Doped and Cr<sup>3+</sup>, Nd<sup>3+</sup> Co-doped Y<sub>3</sub>Al<sub>5</sub>O<sub>12</sub>, Y<sub>3</sub>Al<sub>2</sub>Ga<sub>3</sub>O<sub>12</sub>, and Y<sub>3</sub>Ga<sub>5</sub>O<sub>12</sub> Nanothermometers.

Elzbieciak Karolina K   Marciniak Lukasz L  

Frontiers in chemistry 20180919


A new approach to enhance the sensitivity of transition metal ion based nanocrystalline luminescent thermometer is presented. It was shown that the increase of Cr<sup>3+</sup> concentration in three types of garnet host namely Y<sub>3</sub>Al<sub>5</sub>O<sub>12</sub>, Y<sub>3</sub>Ga<sub>5</sub>O<sub>12</sub>, and Y<sub>3</sub>Al<sub>2</sub>Ga<sub>3</sub>O<sub>12</sub> allows for significant enhancement of their performance in non-contact thermometry. This phenomenon is related to the weakening  ...[more]

Similar Datasets

| S-EPMC8450905 | biostudies-literature
| S-EPMC8289245 | biostudies-literature
| S-EPMC9060535 | biostudies-literature
| S-EPMC5497270 | biostudies-literature
| S-EPMC7684308 | biostudies-literature
| S-EPMC7794296 | biostudies-literature
| S-EPMC9462207 | biostudies-literature
| S-EPMC7841783 | biostudies-literature
| S-EPMC8695478 | biostudies-literature
| S-EPMC10059910 | biostudies-literature