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Temperature dependency of aqueous biphasic systems: an alternative approach for exploring the differences between Coulombic-dominated salts and ionic liquids.

ABSTRACT: Herein we propose an alternative way to distinguish ionic liquids from Coulombic-dominated salts, based not on their upper limit melting temperature (100 °C), but on the trend of their phase-forming abilities to create aqueous biphasic systems as a function of temperature, in which a wider plethora of interactions can be appraised.

SUBMITTER: E Silva FA 

PROVIDER: S-EPMC6157718 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature

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Temperature dependency of aqueous biphasic systems: an alternative approach for exploring the differences between Coulombic-dominated salts and ionic liquids.

E Silva Francisca A FA   Pereira Jorge F B JFB   Kurnia Kiki A KA   Ventura Sónia P M SPM   Silva Artur M S AMS   Silva Artur M S AMS   Rogers Robin D RD   Coutinho João A P JAP   Freire Mara G MG  

Chemical communications (Cambridge, England) 20170427 53

Herein we propose an alternative way to distinguish ionic liquids from Coulombic-dominated salts, based not on their upper limit melting temperature (100 °C), but on the trend of their phase-forming abilities to create aqueous biphasic systems as a function of temperature, in which a wider plethora of interactions can be appraised. ...[more]

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