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Exploring the Gas-Permeation Properties of Proton-Conducting Membranes Based on Protic Imidazolium Ionic Liquids: Application in Natural Gas Processing.

ABSTRACT: This experimental study explores the potential of supported ionic liquid membranes (SILMs) based on protic imidazolium ionic liquids (ILs) and randomly nanoporous polybenzimidazole (PBI) supports for CH?/N? separation. In particular, three classes of SILMs have been prepared by the infiltration of porous PBI membranes with different protic moieties: 1-H-3-methylimidazolium bis (trifluoromethane sulfonyl)imide; 1-H-3-vinylimidazolium bis(trifluoromethane sulfonyl)imide followed by in situ ultraviolet (UV) polymerization to poly[1-(3H-imidazolium)ethylene] bis(trifluoromethanesulfonyl)imide. The polymerization process has been monitored by Fourier transform infrared (FTIR) spectroscopy and the concentration of the protic entities in the SILMs has been evaluated by thermogravimetric analysis (TGA). Single gas permeability values of N? and CH? at 313 K, 333 K and 363 K were obtained from a series of experiments conducted in a batch gas permeance system. The results obtained were assessed in terms of the preferential cavity formation and favorable solvation of methane in the apolar domains of the protic ionic network. The most attractive behavior exhibited poly[1-(3H-imidazolium)ethylene]bis(trifluoromethanesulfonyl)imide polymeric ionic liquid (PIL) cross-linked with 1% divinylbenzene supported membranes, showing stable performance when increasing the upstream pressure. The CH?/N? permselectivity value of 2.1 with CH? permeability of 156 Barrer at 363 K suggests that the transport mechanism of the as-prepared SILMs is solubility-dominated.

SUBMITTER: Kallem P

PROVIDER: S-EPMC6161093 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Exploring the Gas-Permeation Properties of Proton-Conducting Membranes Based on Protic Imidazolium Ionic Liquids: Application in Natural Gas Processing.

Kallem Parashuram P Charmette Christophe C Drobek Martin M Julbe Anne A Mallada Reyes R Pina Maria Pilar MP

Membranes 20180905 3

This experimental study explores the potential of supported ionic liquid membranes (SILMs) based on protic imidazolium ionic liquids (ILs) and randomly nanoporous polybenzimidazole (PBI) supports for CH₄/N₂ separation. In particular, three classes of SILMs have been prepared by the infiltration of porous PBI membranes with different protic moieties: 1-H-3-methylimidazolium bis (trifluoromethane sulfonyl)imide; 1-H-3-vinylimidazolium bis(trifluoromethane sulfonyl)imide followed by in situ ultravi ...[more]

PMID: 30189665

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Project description:Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is one of the most popular conducting polymers and widely used as polymer thermoelectric materials, and its thermoelectric performance could be improved by a variety of post-treatment processes. This paper reported two series of post-treatment methods to enhance the thermoelectric performance. The first series method included pre-treatment of PEDOT:PSS film with formamide, followed by imidazolium-based ionic liquids. The second series method included pre-treatment of PEDOT:PSS film with formamide, followed by sodium formaldehyde sulfoxylate, and finally imidazolium-based ionic liquids. Two series of post-treatment methods significantly improved the power factor of PEDOT:PSS when compared to that of PEDOT:PSS treated with formamide only. For example, using the first series post-treatment method with 40 vol.% ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl) amide, the Seebeck coefficient of the PEDOT:PSS film increased from 14.9 to 28.5 μV/K although the electrical conductivity reduced from 2,873 to 1,701 S/cm, resulting in a substantial improvement in the overall power factor from 63.6 to 137.8 μW/K2m. The electrical conductivity enhancement in the formamide-treatment process was in part ascribed to the removal of the insulating PSS component. Further treatment of PEDOT:PSS film with ionic liquid caused dedoping of PEDOT and hence increased in Seebeck coefficient. In contrast, second series post-treatment method led to the reduction in electrical conductivity from 2,873 to 641 S/cm but a big improvement in the Seebeck coefficient from 14.9 to 61.1 μV/K and thus the overall power factor reached up to ~239.2 μW/K2m. Apart from the improvement in electrical conductivity, the increase in Seebeck coefficient is on account of the substantial dedoping of PEDOT polymer to its neutral form and thus leads to the big improvement of its Seebeck coefficient. The environmental stability of ionic liquid-treated PEDOT:PSS films were examined. It was found that the ionic liquid treated PEDOT:PSS retained more than 70% Seebeck coefficient and electrical conductivity at 75% RH humidity and 70°C for 480 h. The improved long-term TE stability is attributed to the strong ionic interaction between sulfonate anions and bulky imidazolium cations that effectively block the penetration of water and lessen the tendency to take up water from the air.

Dataset Information

Exploring the Gas-Permeation Properties of Proton-Conducting Membranes Based on Protic Imidazolium Ionic Liquids: Application in Natural Gas Processing.

Publications

Exploring the Gas-Permeation Properties of Proton-Conducting Membranes Based on Protic Imidazolium Ionic Liquids: Application in Natural Gas Processing.

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