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Facile synthesis of palladium nanoparticles on hierarchical hollow silica spheres and its catalytic properties in Suzuki-reaction.


ABSTRACT: A novel well-dispersed Pd@HHSS catalyst was synthesized by reduction of Pd(OAc)2 immobilized on HHSS we reported. When the ratios of Pd/SiO2 were 5 : 100 and 10 : 100, the Pd nanoparticles size was about 5-10 nm. The Pd@HHSS catalyst (Pd/SiO2 = 10 : 100) showed high catalytic activity in Suzuki-reaction with yields of 91-99% and the catalyst is reusable after four successive cycles without obvious loss of catalytic activity.

SUBMITTER: Liu M 

PROVIDER: S-EPMC6170588 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Facile synthesis of palladium nanoparticles on hierarchical hollow silica spheres and its catalytic properties in Suzuki-reaction.

Liu Mao M   Wu Liuli L   Han Jianjie J   Xu Xiuhong X   He Chengyuan C   Wang Peng P   Wei Qian Q   Yang Wanliang W  

Royal Society open science 20180912 9


A novel well-dispersed Pd@HHSS catalyst was synthesized by reduction of Pd(OAc)<sub>2</sub> immobilized on HHSS we reported. When the ratios of Pd/SiO<sub>2</sub> were 5 : 100 and 10 : 100, the Pd nanoparticles size was about 5-10 nm. The Pd@HHSS catalyst (Pd/SiO<sub>2</sub> = 10 : 100) showed high catalytic activity in Suzuki-reaction with yields of 91-99% and the catalyst is reusable after four successive cycles without obvious loss of catalytic activity. ...[more]

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