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On-Chip Asymmetric Microsupercapacitors Combining Reduced Graphene Oxide and Manganese Oxide for High Energy-Power Tradeoff.


ABSTRACT: Given the rapid miniaturization of technology, it is of interest to produce viable on-chip micro-electrochemical energy storage systems. In this study, interdigitated asymmetric microsupercapacitors were fabricated using photolithography, lift-off and electrodeposition methods. Manganese oxide (MnOx) and reduced graphene oxide (rGO) comprised the pseudocapacitive and the double layer component, respectively. Symmetric MnOx//MnOx, rGO//rGO as well as asymmetric rGO//MnOx microsupercapacitors with three different MnOx thicknesses were constructed and characterized in aqueous media. The asymmetric microsupercapacitor with the intermediate MnOx film thickness displayed the optimal energy-power trade-off superior to that of both the symmetric and well as the other asymmetric configurations. The optimal microsupercapacitor exhibited a high stack energy density of 1.02 mWh·cm-3 and a maximal power density of 3.44 W·cm-3. The high energy-power trade-off of the device is attributed to the synergistic effects of utilizing double layer and pseudocapacitive charge storage mechanisms along with in-plane interdigital microelectrode design within one optimized micro-device.

SUBMITTER: Agrawal R 

PROVIDER: S-EPMC6187318 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature

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On-Chip Asymmetric Microsupercapacitors Combining Reduced Graphene Oxide and Manganese Oxide for High Energy-Power Tradeoff.

Agrawal Richa R   Wang Chunlei C  

Micromachines 20180812 8


Given the rapid miniaturization of technology, it is of interest to produce viable on-chip micro-electrochemical energy storage systems. In this study, interdigitated asymmetric microsupercapacitors were fabricated using photolithography, lift-off and electrodeposition methods. Manganese oxide (MnO<sub>x</sub>) and reduced graphene oxide (rGO) comprised the pseudocapacitive and the double layer component, respectively. Symmetric MnO<sub>x</sub>//MnO<sub>x</sub>, rGO//rGO as well as asymmetric rG  ...[more]

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